thanks so much everyone! i appreciate the pointers. Bandjob is such a fun source for inspiration i thought i'd ask for some tips
Derek:

i will definitely play more with selective color & balance more than i do, thanks!
Randomentity:
thanks so much! light leak is a big one, and i didn't just want to always be airbrushing a color all slapdash. thanks!
Godmachine:
those are a great starting point, makes me want to leanr this by picking up a real camera. thank you!
Uzi:
my browser isn't showing your comment, but your Caliban shirt bowled me over dude, we need to see more please
ArmyofCats:
you rock, thank you so much. experimentation has always been one of my best teachers. and i don't always succeed, but i try to worship at the church of subtlety. my goal is to try and work densely enough that it doesn't scream "photoshop!" but now that i've been lurking here and i'm so in awe of everybody here, i realize how very novice i still am now that my circle of peers widened so much. i really appreciate both your tips as well as your insight